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## Slant Column and Vertical Column Densities

Nadir-viewing satellite based instruments, such as SCIAMACHY and GOME-2, measure the sunlight scattered in the atmosphere and reflected by the surface of the Earth, as function of the wavelength of the light. In other words: the instruments measure earthshine spectra. Comparing such a spectrum with the spectrum of the sunlight itself provides information on the distribution and concentration of trace gases, such as ozone and SO2, because these gases absorb or scatter part of the incoming sunlight (instead of using the solar spectrum for this comparison, one can also use an earthshine spectrum from a part of the atmosphere free of the trace gases under study).

### Cloud free case

Schematic representation of the slant path (thick red lines) of incoming sunlight through the earth's atmosphere to the satellite, associated with the footpoint F (the point on the earth's surface the satellite is looking at). A part of the light reaching the satellite is reflected by the earth's surface, another part is scattered higher in the atmosphere. The thick blue line represents the "vertical column" at footpoint F.

The above graph shows schematically the paths of sunlight reaching the satellite through the atmosphere, reflected by the earth's surface and scattered in the atmosphere. As the light follows these paths, some of the photons are absorbed by the trace gases in the atmosphere. The spectrum of the light measured by the satellite (the sum, as it where, of the thick red lines in the graph) thus provides information on the trace gases along the entire light path. In other words, the total density of a given gas, such as SO2, is the concentration of this gas along the entire path. This is usually called the slant column density (SCD) associated with footpoint F, the point on the earth's surface the satellite is looking at.

The SCD clearly does not provide the total concentration right above footpoint F, i.e. along the blue line in the graph. The total concentration along this line is called the vertical column density (VCD). It is this VCD that provides the most useful and directly interpretable information on the distribution and concentration of trace gases. It is therefore desirable to convert the SCD into the VCD.

As can be seen from the graph above, the VCD (along the blue line) is usually smaller than the SCD (along the red lines). The ratio between these two column densities:

AMF = SCD / VCD

is called the Air-Mass Factor. The value of the AMF depends on the length of the light path, the vertical distribution of absorbing trace gases in the atmosphere, the reflectivity (albedo) of the earth's surface, etc. The length of the light path depends on the position of the Sun (expressed in the Solar Zenith Angle, SZA) and the angle under which the satellite is looking at the atmosphere. The AMF can be pre-calculated for a variety of these quantities or computed with a chemistry transport model, and applied to the SCD to find the VCD at footpoint F.

### Partly clouded case

Schematic representation of the slant path (thick red lines) of incoming sunlight through the earth's atmosphere to the satellite, associated with the footpoint F (the point on the earth's surface the satellite is looking at), in the presence of clouds. These clouds partly shield the satellite's view of the atmosphere above footpoint F.

If there are clouds in the atmosphere, things become more complicated. Clouds namely reflect (and scatter) incoming sunlight and thus effectively shield all that is going on below the clouds from the satellite's view. Clearly, the satellite measurements provide an SCD which contains only information on the atmosphere above the clouds. To find the real VCD at footpoint F in such situations, an "effective" AMF is computed, taking the cloud fraction (which gives the percentage of the cloud cover) into account. In the presence of clouds the VCD is clearly less accurate than the VCD derived under clear-sky conditions.

There are two approaches possible to convert the SO2 slant column density, retrieved with a DOAS technique, into a vertical column density. Both of these approaches use an air-mass factor (AMF), and they are described elsewhere in these pages:

Last update on 09 Dec 2010